Neutrons, electrons, and theory reveal secrets of natural gas reserves

Scanning Electronic Microscope Image of Unconventional Gas Reservoir

A scanning electron microscope image illustrating mineralogy and texture of an unconventional gas reservoir. Note that nanoporosity is not resolvable with this image. SANS and USANS analysis is required to quantify pore size distribution and interconnectivity. (Photo courtesy Oak Ridge National Laboratory)

Gas and oil deposits in shale have no place to hide from an Oak Ridge National Laboratory technique that provides an inside look at pores and reveals structural information potentially vital to the nation’s energy needs.

The research by scientists at the U.S. Department of Energy laboratory could clear the path to the more efficient extraction of gas and oil from shale, environmentally benign and efficient energy production from coal, and perhaps viable carbon dioxide sequestration technologies, according to Yuri Melnichenko, an instrument scientist at ORNL’s High Flux Isotope Reactor.

Melnichenko’s broader work was emboldened by a collaboration with James Morris and Nidia Gallego, lead authors of a paper recently published in Journal of Materials Chemistry A and members of ORNL’s Materials Science and Technology Division.

Researchers were able to describe a small-angle neutron scattering technique that, combined with electron microscopy and theory, can be used to examine the function of pore sizes.

Using their technique at the General Purpose SANS instrument at the High Flux Isotope Reactor, scientists showed there is significantly higher local structural order than previously believed in nanoporous carbons. This is important because it allows scientists to develop modeling methods based on local structure of carbon atoms. Researchers also probed distribution of adsorbed gas molecules at unprecedented smaller length scales, allowing them to devise models of the pores.

“We have recently developed efficient approaches to predict the effect of pore size on adsorption,” Morris said. “However, these predictions need verification—and the recent small-angle neutron experiments are ideal for this. The experiments also beg for further calculations, so there is much to be done.”

While traditional methods provide general information about adsorption averaged over an entire sample, they do not provide insight into how pores of different sizes contribute to the total adsorption capacity of a material. Unlike absorption, a process involving the uptake of a gas or liquid in some bulk porous material, adsorption involves the adhesion of atoms, ions, or molecules to a surface.

This research, in conjunction with previous work, allows scientists to analyze two-dimensional images to understand how local structures can affect the accessibility of shale pores to natural gas.

“Combined with atomic-level calculations, we demonstrated that local defects in the porous structure observed by microscopy provide stronger gas binding and facilitate its condensation into liquid in pores of optimal sub-nanometer size,” Melnichenko said. “Our method provides a reliable tool for probing properties of sub- and super-critical fluids in natural and engineered porous materials with different structural properties.

“This is a crucial step toward predicting and designing materials with enhanced gas adsorption properties.”

Together, the application of neutron scattering, electron microscopy, and theory can lead to new design concepts for building novel nanoporous materials with properties tailored for the environment and energy storage-related technologies. These include capture and sequestration of man-made greenhouse gases, hydrogen storage, membrane gas separation, environmental remediation, and catalysis.

Other authors of the paper, titled “Modern approaches to studying gas adsorption in nanoporous carbons,” are Cristian Contescu, Matthew Chisholm, Valentino Cooper, Lilin He, Yungok Ihm, Eugene Mamontov, Raina Olsen, Stephen Pennycook, Matthew Stone, and Hongxin Zhang. The research, funded by DOE’s Office of Basic Energy Sciences, used the following DOE Office of Science user facilities:

ORNL’s Spallation Neutron Source is a one-of-a-kind research facility that provides the most intense pulsed neutron beams in the world for scientific research and industrial development.

HFIR at ORNL is a light-water cooled and moderated reactor that is the United States’ highest flux reactor-based neutron source.

The ShaRE User Facility makes available state-of-the-art electron beam microcharacterization facilities for collaboration with researchers from universities, industry and other government laboratories.

As a national resource to enable scientific advances to support the missions of DOE’s Office of Science, the National Energy Research Scientific Computing Center, annually serves approximately 3,000 scientists throughout the United States.

UT-Battelle manages ORNL for the Department of Energy’s Office of Science. DOE’s Office of Science is the single largest supporter of basic research in the physical sciences in the United States, and is working to address some of the most pressing challenges of the time. For more information, visit science.energy.gov.

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