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‘Atomic switcheroo’ explains origins of thin-film solar cell mystery

Posted at 10:40 am May 4, 2014
By Oak Ridge Today Staff Leave a Comment

Current Maps

Cross-sectional electron beam-induced current maps show the difference in cadmium telluride solar cells before (pictured above) and after (below) cadmium chloride treatment. The increased brightness after treatment indicates higher current collection at the grain boundaries. (Submitted photo)

Treating cadmium-telluride (CdTe) solar cell materials with cadmium-chloride improves their efficiency, but researchers have not fully understood why. Now, an atomic-scale examination of the thin-film solar cells led by Oak Ridge National Laboratory has answered this decades-long debate about the materials’ photovoltaic efficiency increase after treatment.

A research team from ORNL, the University of Toledo, and the U.S. Department of Energy’s National Renewable Energy Laboratory used electron microscopy and computational simulations to explore the physical origins of the unexplained treatment process. The results are published in Physical Review Letters, or PRL.

Thin-film CdTe solar cells are considered a potential rival to silicon-based photovoltaic systems because of their theoretically low cost per power output and ease of fabrication. Their comparatively low historical efficiency in converting sunlight into energy, however, has limited the technology’s widespread use, especially for home systems. [Read more…]

Filed Under: Front Page News, Oak Ridge National Laboratory, Science, U.S. Department of Energy Tagged With: Andrew Lupini, cadmium-chloride, cadmium-telluride, CdTe, cell efficiency, Center for Nanophase Materials Sciences, Chen Li, chlorine, CNMS, DOE, energy, Grain-Boundary-Enhanced Carrier Collection in CdTe Solar Cells, Jonathan Poplawsky, Mark Oxley, Mowafak Al-Jassim, Naba Paudel, Nanoscale Science Research Centers, National Energy Research Scientific Computing Center, National Renewable Energy Laboratory, NREL, NSRC, Oak Ridge National Laboratory, Office of Basic Energy Sciences, Office of Energy Efficiency and Renewable Energy, Ohio Research Scholar Program, ORNL, Physical Review Letters, PRL, Sarah Haigh, solar cell, Stephen Pennycook, sunlight, SunShot Initiative, tellurium, Timothy Pennycook, U.S. Department of Energy, UK Engineering and Physical Sciences Research Council, University of Manchester, University of Oxford, University of Tennessee, University of Toledo, Vanderbilt University, Wanjian Yin, Yanfa Yan, Yelong Wu

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