ORNL-grown oxygen ‘sponge’ presents path to better catalysts, energy materials

Scientists at Oak Ridge National Laboratory have developed a new oxygen “sponge” that can easily absorb or shed oxygen atoms at low temperatures. Materials with these novel characteristics would be useful in devices such as rechargeable batteries, sensors, gas converters, and fuel cells.

Materials containing atoms that can switch back and forth between multiple oxidation states are technologically important but very rare in nature, said ORNL’s Ho Nyung Lee, who led the international research team that published its findings in Nature Materials.

“Typically, most elements have a stable oxidation state, and they want to stay there,” Lee said. “So far, there aren’t many known materials in which atoms are easily convertible between different valence states. We’ve found a chemical substance that can reversibly change between phases at rather low temperatures without deteriorating, which is a very intriguing phenomenon.”

Many energy storage and sensor devices rely on this valence-switching trick, known as a reduction-oxidation or “redox” reaction. For instance, catalytic gas converters use platinum-based metals to transform harmful emissions such as carbon monoxide into nontoxic gases by adding oxygen. Less expensive oxide-based alternatives to platinum usually require very high temperatures—at least 600 to 700 degrees Celsius—to trigger the redox reactions, making such materials impractical in conventional applications.

“We show that our multivalent oxygen sponges can undergo such a redox process at as low as 200 degrees Celsius, which is comparable to the working temperature of noble metal catalysts,” Lee said. “Granted, our material is not coming to your car tomorrow, but this discovery shows that multivalent oxides can play a pivotal role in future energy technologies.”

The team’s material consists of strontium cobaltite, which is known to occur in a preferred crystalline form called brownmillerite. Through an epitaxial stabilization process, the ORNL-led team discovered a new recipe to synthesize the material in a more desirable phase known as perovskite. The researchers have filed an invention disclosure on their findings.

“These two phases have very distinct physical properties,” Lee said. “One is a metal, the other is an insulator. One responds to magnetic fields, the other does not—and we can make it switch back and forth within a second at significantly reduced temperatures.”

The international team’s design and testing of this novel advanced material from scratch required multidisciplinary expertise and sophisticated tools from such places as Argonne National Laboratory and ORNL, including Argonne’s Advanced Photon Source and ORNL’s Center for Nanophase Materials Science, Lee said.

“As we showed in this study, only through the study of a well-defined system can we build a framework for the design of next-generation energy materials,” said co-author John Freeland of Argonne. “This insight was made possible by merging the capabilities at Oak Ridge and Argonne national labs for advanced synthesis and characterization of novel materials.”

The study, “Reversible redox reactions in an epitaxially stabilized SrCoOx oxygen sponge,” involved ORNL’s Hyoungjeen Jeen, Woo Seok Choi, Matthew Chisholm, Michael Biegalski, and Dongwon Shin; Argonne’s Chad Folkman, I-Cheng Tung, Dillon Fong, and John Freeland; and Hokkaido University’s Hiromichi Ohta.

The work was supported by the U.S. Department of Energy’s Office of Science.

The Advanced Photon Source at Argonne National Laboratory is one of five national synchrotron radiation light sources supported by DOE’s Office of Science to carry out applied and basic research to understand, predict, and ultimately control matter and energy at the electronic, atomic, and molecular levels, provide the foundations for new energy technologies, and support DOE missions in energy, environment, and national security. To learn more about the Office of Science X-ray user facilities, visit the user facilities directory at http://science.energy.gov/user-facilities/basic-energy-sciences/.

The Center for Nanophase Materials Science is one of five DOE Nanoscale Science Research Centers, or NSRCs, national user facilities for interdisciplinary research at the nanoscale, supported by the DOE Office of Science. Together the NSRCs comprise a suite of complementary facilities that provide researchers with state-of-the-art capabilities to fabricate, process, characterize, and model nanoscale materials, and constitute the largest infrastructure investment of the National Nanotechnology Initiative. The NSRCs are located at DOE’s Argonne, Brookhaven, Lawrence Berkeley, Oak Ridge and Sandia and Los Alamos National Laboratories. For more information about the DOE NSRCs, please visit http://science.energy.gov.

ORNL is managed by UT-Battelle for the Department of Energy’s Office of Science. DOE’s Office of Science is the single largest supporter of basic research in the physical sciences in the United States, and is working to address some of the most pressing challenges of our time. For more information, please visit http://science.energy.gov.