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ORNL demonstrates first large-scale graphene composite fabrication

Posted at 11:55 am May 19, 2015
By Oak Ridge National Laboratory 1 Comment

ORNL Graphene

ORNL’s ultrastrong graphene features layers of graphene and polymers and is an effective conductor of electricity. (Image courtesy ORNL)

 

One of the barriers to using graphene at a commercial scale could be overcome using a method demonstrated by researchers at the U.S. Department of Energy’s Oak Ridge National Laboratory.

Graphene, a material stronger and stiffer than carbon fiber, has enormous commercial potential but has been impractical to employ on a large scale, with researchers limited to using small flakes of the material.

Now, using chemical vapor deposition, a team led by ORNL’s Ivan Vlassiouk has fabricated polymer composites containing 2-inch-by-2-inch sheets of the one-atom thick hexagonally arranged carbon atoms.

The findings, reported in the journal Applied Materials & Interfaces, could help usher in a new era in flexible electronics and change the way this reinforcing material is viewed and ultimately used.

“Before our work, superb mechanical properties of graphene were shown at a micro scale,” said Vlassiouk, a member of ORNL’s Energy and Transportation Science Division. “We have extended this to a larger scale, which considerably extends the potential applications and market for graphene.”

While most approaches for polymer nanocomposition construction employ tiny flakes of graphene or other carbon nanomaterials that are difficult to disperse in the polymer, Vlassiouk’s team used larger sheets of graphene. This eliminates the flake dispersion and agglomeration problems and allows the material to better conduct electricity with less actual graphene in the polymer.

“In our case, we were able to use chemical vapor deposition to make a nanocomposite laminate that is electrically conductive with graphene loading that is 50 times less compared to current state-of-the-art samples,” Vlassiouk said. This is a key to making the material competitive on the market.

If Vlassiouk and his team can reduce the cost and demonstrate scalability, researchers envision graphene being used in aerospace (structural monitoring, flame-retardants, anti-icing, conductive), the automotive sector (catalysts, wear-resistant coatings), structural applications (self-cleaning coatings, temperature control materials), electronics (displays, printed electronics, thermal management), energy (photovoltaics, filtration, energy storage) and manufacturing (catalysts, barrier coatings, filtration).

Co-authors of the paper, titled “Strong and Electrically Conductive Graphene Based Composite Fibers and Laminates,” are Georgious Polizos, Ryan Cooper, Ilia Ivanov, Jong Kahk Keum, Felix Paulauskas, and Panos Datksos of ORNL and Sergei Smirnov of New Mexico State University. The paper is available here.

The research was supported by ORNL’s Laboratory Directed Research and Development program. A portion of the work was conducted at the Center for Nanophase Materials Sciences, a DOE Office of Science User Facility.

Filed Under: Front Page News, Oak Ridge National Laboratory, U.S. Department of Energy Tagged With: Applied Materials and Interfaces, carbon fiber, Center for Nanophase Materials Sciences, Energy and Transportation Science Division, Felix Paulauskas, flexible electronics, Georgious Polizos, graphene, Ilia Ivanov, Ivan Vlassiouk, Jong Kahk Keum, Laboratory Directed Research and Development, New Mexico State University, Oak Ridge National Laboratory, Office of Science, ORNL, Panos Datksos, polymer, Ryan Cooper, Sergei Smirnov, Strong and Electrically Conductive Graphene Based Composite Fibers and Laminates, U.S. Department of Energy

Comments

  1. Mark Caldwell says

    May 21, 2015 at 2:18 pm

    “How beauteous mankind is! O brave new world, That has such people in’t”

    Reply

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